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Generation of surface steps on Pt(9 7 7) induced by the catalytic oxidation of CO

1-s2.0-S0021951713003230-fx1

O. BalmesG. PrevotX. TorrellesE. LundgrenS. Ferrer.
Journal of Catalysis Volume 309, January 2014, Pages 33–37

 

DOI: http://dx.doi.org/10.1016/j.jcat.2013.09.001

 

The catalytic oxidation of CO has been investigated on the stepped Pt(9 7 7) surface at near ambient pressure and elevated temperature. It has been found that the reactivity is maximum at approximately the stoichiometric proportion of reactants and that surface monoatomic steps are generated by the reaction itself, being most abundant when the reaction proceeds with maximum efficiency.

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